|
|
dihydroceramide + H2O <=> sphinganine + a_carboxylate
|
3.5.1.23
ceramidase
|
–
|
| |
MetaCyc:
RXN-13733
|
|
|
|
Pentadecanoate + CoA + ATP <=> S-(2-oxo)pentadecyl-CoA + diphosphate + AMP
|
6.2.1.3
long-chain-fatty-acid---CoA ligase
|
–
|
| |
BRENDA:
BS294
MetaCyc:
RXN-20651
|
|
|
|
phytosphingosine + ATP <=> phytosphingosine_1-phosphate + ADP + H+
|
2.7.1.91
sphingosine kinase
|
–
|
| |
BRENDA:
BS378570
MetaCyc:
RXN-20648;
RXN3O-458
|
|
|
|
sphinganine_1-phosphate + H2O <=> sphinganine + phosphate
|
3.1.3
3.1.3.4
phosphatidate phosphatase
|
–
–
|
| |
BRENDA:
BS391833
KEGG:
R06520
MetaCyc:
DHS-PHOSPHATASE-RXN
SABIO-RK:
6096
|
|
|
|
IpC + H2O <=> very-long-chain_(2''R)-2''-hydroxy-phytoceramide + D-myo-Inositol_1-phosphate + H+
|
3.1.4
|
–
|
| |
MetaCyc:
RXN-13730
|
|
|
|
hexadecanal + NAD+ + H2O <=> fatty_acid + NADH + H+
|
1.2.1.3
aldehyde dehydrogenase (NAD+)
1.2.1.47
4-trimethylammoniobutyraldehyde dehydrogenase
1.2.1.48
long-chain-aldehyde dehydrogenase
1.2.1.5
aldehyde dehydrogenase [NAD(P)+]
|
–
–
–
–
|
| |
BRENDA:
BR36783
KEGG:
R01704;
R02039
MetaCyc:
LONG-CHAIN-ALDEHYDE-DEHYDROGENASE-RXN;
RXN-16655
SABIO-RK:
1816
|
|
|
|
(R)-2-hydroxyhexadecanoate + O2 <=> Pentadecanoate + CO2 + H2O
|
1.14.18.12
2-hydroxy fatty acid dioxygenase
|
–
|
| |
BRENDA:
BS448359
MetaCyc:
RXN-20650
|
|
|
|
phytosphingosine_1-phosphate <=> (R)-2-hydroxyhexadecanal + Phosphoethanolamine
|
4.1.2.27
sphinganine-1-phosphate aldolase
|
–
|
| |
MetaCyc:
RXN-13729
|
|
|
|
a_very-long-chain_mannosyl-diphosphoinositol-(2'R)-2'-hydroxyphytoceramide + H2O <=> very-long-chain_(2''R)-2''-hydroxy-phytoceramide + phosphoinositol-alpha-mannoside-phosphoinositol
|
3.1.4
|
–
|
| |
MetaCyc:
RXN-13732
|
|
|
|
(R)-2-hydroxyhexadecanal + NAD+ + H2O <=> (R)-2-hydroxyhexadecanoate + NADH + H+
|
1.2.1.3
aldehyde dehydrogenase (NAD+)
|
–
|
| |
MetaCyc:
RXN-20649
|
|
|
|
very-long-chain_(2''R)-2''-hydroxy-phytoceramide + H2O <=> phytosphingosine + very-long-chain_(2R)-2-hydroxy_fatty_acid
|
3.5.1.23
ceramidase
|
–
|
| |
MetaCyc:
CERAMIDASE-YEAST-RXN
|
|
|
|
sphinganine_1-phosphate <=> hexadecanal + Phosphoethanolamine
|
4.1.2.27
sphinganine-1-phosphate aldolase
|
–
|
| |
BRENDA:
BR359
KEGG:
R02464
MetaCyc:
SPHINGANINE-1-PHOSPHATE-ALDOLASE-RXN
|
|
|
|
a_very-long-chain_mannosylinositol_phospho-(2'R)-2'-hydroxyphytoceramide + H2O <=> very-long-chain_(2''R)-2''-hydroxy-phytoceramide + phosphoinositol-alpha-mannoside + H+
|
3.1.4
|
–
|
| |
MetaCyc:
RXN-13731
|
|
|
|
sphinganine + ATP <=> H+ + sphinganine_1-phosphate + ADP
|
2.7.1.91
sphingosine kinase
|
–
|
| |
BRENDA:
BS370403
KEGG:
R02976
MetaCyc:
SPHINGANINE-KINASE-RXN
SABIO-RK:
2830
|
|
|
|
fatty_acid + CoA + ATP <=> stearoyl-CoA + AMP + diphosphate
|
1.13.12.7
firefly luciferase
6.2.1.12
4-coumarate---CoA ligase
6.2.1.3
long-chain-fatty-acid---CoA ligase
6.2.1.30
phenylacetate---CoA ligase
6.2.1.B3
|
–
–
–
–
–
|
| |
BRENDA:
BR82;
BS287
KEGG:
R00390;
R01280
MetaCyc:
RXN-16380;
RXN-7904;
RXN-9623
SABIO-RK:
10953;
1496
|
|
|
|
phytosphingosine_1-phosphate + H2O <=> phytosphingosine + phosphate
|
3.1.3
|
–
|
| |
MetaCyc:
RXN3O-504
|
|
